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Enhancing the Performance of Nickel Electrocatalysts for the Oxygen Evolution Reaction Using Arrays of Self-Cleaning Linear Ridges

Resource type
Date created
2024-03-21
Authors/Contributors
Author: Rea, Alex
Author: Gates, Byron
Abstract
The oxygen evolution reaction represents a key source of inefficiency for green hydrogen production. In general, persistent bubbles that grow on the surfaces of an electrode obstruct a portion of the electrochemically active surface area, resulting in a decreased overall efficiency. Microscale features on the surfaces of electrocatalysts can, however, aid in the removal of these adherent bubbles. Gas production and conversion efficiencies have been shown to improve when incorporating linear, ridge-like microscale features onto electrodes. These factors improve with an increase in the separation between these ridges as demonstrated for features with separations up to 200 μm, but the full extent of this trend is not known. In this study, a series of linear, ridge-like features were prepared to seek a separation between these features that yields an optimal performance. The ridge-like features were prepared from nickel (Ni) using microscope project lithography techniques in combination with Ni electrodeposition, which was demonstrated to be a versatile technique for rapidly prototyping these features. At an industrially relevant potential of 1.8 V [vs mercury/mercury oxide (Hg/HgO)] in an alkaline electrolyte, the performance of arrays of the ridge-like features were observed to increase up to a critical separation of ~300 μm, beyond which the performance decreased and approached that of planar Ni electrocatalysts. At this identified critical separation of features, the current response under chronoamperometry conditions was nearly triple that obtained for the planar Ni electrocatalysts. Observations of growth, coalescence, and detachment of gas bubbles on the microscale ridge-like features achieved using high-speed imaging suggest a possible cause for the improved performance at the identified optimal spacing of the arrays of linear features.
Description
Fulltext of the document is not available until March 2025 due to the journal embargo policies of the American Chemical Society. If you need fulltext access please email summit@sfu.ca.
Accepted date
26 March 2024
Available date
27 March 2025
Publication title
ACS Applied Energy Materials
Document title
Enhancing the Performance of Nickel Electrocatalysts for the Oxygen Evolution Reaction Using Arrays of Self-Cleaning Linear Ridges
Publisher
American Chemical Society
Date
2024-03-21
Copyright statement
Copyright is held by the publisher with many rights continuing to also be held by the author(s).
Scholarly level
Peer reviewed?
Yes
Member of collection

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