Resource type
Date created
2019-04-24
Authors/Contributors
Author: Herasymchuk, Khrystyna
Author: Miller, Jessica J.
Author: MacNeil, Gregory A.
Author: Sergeenko, Ania S.
Author: McKearney, Declan
Author: Goeb, Sébastien
Author: Sallé, Marc
Author: Leznoff, Daniel B.
Author: Storr, Tim
Abstract
The design and synthesis of a supramolecular square was achieved by coordination-driven assembly of redox-active nickel(II) salen linkers and (ethylenediamine)palladium(II) nodes. The tetrameric geometry of the supramolecular structure was confirmed via MS, NMR, and electrochemical experiments. While oxidation of the monomeric metalloligand Schiff-base affords a Ni(III) species, oxidation of the coordination-driven assembly results in ligand radical formation.
Document
Identifier
DOI: 10.1039/C9CC02320H
Publication details
Publication title
Chemical Communications
Document title
Coordination-driven assembly of a supramolecular square and oxidation to a tetra-ligand radical species
Date
2019-05-28
Volume
55
Issue
43
First page
6082
Last page
6085
Publisher DOI
Published article URL
Copyright statement
Copyright is held by the author(s).
Scholarly level
Peer reviewed?
Yes
Member of collection