The intermediate-valence compound SmB6 is a well-known Kondo insulator, in which the hybridization of itinerant 5d electrons with localized samarium (Sm) 4f electrons leads to the opening of an insulating gap in the bulk. Yet in contrast to expectations for a Kondo insulator, SmB6 exhibits a low-temperature resistivity plateau due to the presence of metallic surface states, as well as low-temperature bulk magnetism of unknown origin. The presence of low-temperature bulk magnetism in SmB6 is also seemingly at odds with recent studies that suggest SmB6 is a topological insulator, with time-reversal symmetry protected metallic surface states emerging from a fully insulating hybridized bulk band structure. This thesis is an investigation of the bulk magnetic properties of SmB6 via magnetic susceptibility and muon spin rotation/relaxation (μSR) measurements. Similar measurements were also performed on 0.5% Fe-doped SmB6 for which Fe substitutes for Sm. The study of 0.5% Fe-doped SmB6 was undertaken to gain insight into the effect of magnetic impurities on the low-temperature magnetic properties of SmB6. Single crystals of pure SmB6 and the 0.5% Fe-SmB6 were grown by an Al-flux method. The bulk magnetic susceptibility measurements for both samples show a Curie-Weiss behaviour above 100 K, indicative of the presence of paramagnetic Sm-4f moments. A magnetic-field dependent upturn in thetemperature dependence of the magnetic susceptibility observed below 15 K in pure SmB6 is attributed to the presence of paramagnetic impurities and/or Sm vacancies. This is corroborated by an enhancement of the low-temperature upturn in the 0.5% Fe-SmB6 sample. The μSR results collectively provide evidence for the existence of bulk magnetic excitations at temperatures below 20 K. In particular, evidence is provided for the existence of a bulk magnetic excitation on the order of 1 meV, compatible with the existence of magnetic in-gap states and in particular a low-energy spin exciton. In addition, underlying low energy (100 neV) weak magnetic fluctuations are observed to persist down to at least 0.024 K. Similar forms of magnetism are observed in the candidate topological Kondo insulator YbB12, suggesting a common origin. Even so, intrinsic defects cannot be ruled out as a potential source of the low-temperature magnetism in SmB6.
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Thesis advisor: Sonier, Jeff
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