Double layer of Platinum Electrodes: Non-Monotonic Surface Charging Phenomena and Negative Double Layer Capacitance

Resource type
Date created
2018-01
Authors/Contributors
Author: Huang, Jun
Author: Zhou, Tao
Abstract
In this study, the refined double layer model of platinum electrodes accounts for chemisorbed oxygen species, oriented interfacial water molecules and ion size effects in solution. It results in a non-monotonic surface charging relation and a peculiar capacitance vs. potential curve with a maximum and maybe negative-defined values in the potential regime of oxide-formation.
Document
Identifier
DOI: 10.1063/1.5010999
Published as
Jun Huang, Tao Zhou, Jianbo Zhang, and Michael Eikerling,Double layer of platinum electrodes: Non-monotonic surface charging phenomena and negative double layer capacitance, Journal of Chemical Physics. 148, 044704 (2018). https://doi.org/10.1063/1.5010999
Publication title
Journal of Chemical Physics
Document title
Double layer of Platinum Electrodes: Non-Monotonic Surface Charging Phenomena and Negative Double Layer Capacitance
Date
2018
Publisher DOI
10.1063/1.5010999
Copyright statement
Copyright is held by the author(s).
Scholarly level
Peer reviewed?
Yes
Language
Member of collection
Attachment Size
1.5010999.pdf 2.99 MB