Resource type
Date created
2016-09
Authors/Contributors
Abstract
The Pd-catalyzed direct alkylation of H-phosphinic acids and hypophosphorous acid with allylic/benzylic alcohols has been described previously. Here, the extension of this methodology to H-phosphinate esters is presented. The new reaction appears general, although its scope is narrower than with the acids, and its mechanism is likely different. Various alcohols are examined in their reaction with phosphinylidene compounds R1R 2P(O)H.
Document
Published as
Fers-Lidou A, Berger O, Montchamp JL. "Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols." Molecules. 2016 Sep 28;21(10).
Publication details
Publication title
Molecules
Document title
Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols
Date
2016
Volume
21
Issue
10
Rights (standard)
Copyright statement
Copyright is held by the author(s).
Scholarly level
Peer reviewed?
Yes
Language
English
Member of collection
| Download file | Size |
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| publication_molecules_montchamp.pdf | 1.49 MB |